Journal
CHEMISTRY OF MATERIALS
Volume 22, Issue 5, Pages 1776-1781Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cm9032513
Keywords
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Funding
- Ministry of Education, Culture, Sports, Science and Tech (MEXT), Japan
- Grants-in-Aid for Scientific Research [22350062] Funding Source: KAKEN
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Superlattice structures (SLSs) assembled with cube-shaped EuS nanocrystals (NCs) and their remarkable magnetic properties are reported. The cube-shaped EuS NCs are prepared by the thermal reduction of single source precursor, tetra(diethyldithiocarbamate) europium complex with oleylamine as a surface modified regent. The fine structures of the three-dimensional (3D) SLSs assembled with EuS NCs are characterized by TEM, small-angle XRD, and electron transmission tomographic analysis. Magnetic measurements of the SLSs on polymer films with SQUID show that the coercive field of the SLSs assembled with cube-shaped EuS NCs are twice larger than those of cube-shaped EuS NCs powder. The enhanced magnetic properties are attributed to magnetic dipole interaction between cube-shaped EuS NCs in SLS structures.
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