Journal
CHEMISTRY OF MATERIALS
Volume 22, Issue 4, Pages 1462-1471Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cm9026607
Keywords
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Funding
- DFG [MO 1049/5-1, ME 1256/7-1, ME 1256/13-1]
- BMBF [03WKBH2G]
- Program Mikhail Lomonosov joint Grant of DAAD [A/06/91419]
- RNP [2.2.2.3.10063]
- European Union
- CENPES/PETRO-BRAS
- CNPq
- FAPERJ
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Biological materials are a rewarding area of modern materials science, yielding both evolutionary insights and inspiration for biomimetic research. In particular, biocomposite structures are valuable sources of novel structures with unusual chemical properties, and they are very informative for the mechanisms of biomineralization. Here we describe a unique biocomposite of amorphous silica, crystalline aragonite, and chitin from species of the order Verongida, a group of marine sponges. The structures have been analyzed with a diverse suite of techniques, revealing a chitinous template for siliceous overgrowth containing aragonite-based crystal aggregates. Sponge chitin is an example of a specific template where two minerals in amorphous and crystalline forms are formed together with an organic molecule.
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