Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 43, Pages 12649-12653Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201506066
Keywords
allenes; copper; fluorine; radicals; transition metals
Categories
Funding
- NNSFC [21202014, 21372041, 21172033]
- SRFDP [20120043120009]
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The first controllable, regioselective radical amination of allenes with N-fluoroarylsulfonimide is described to proceed under very mild reaction conditions. With this methodology, a general and straightforward route for the synthesis of both allenamides and fluorinated tetrasubstituted alkenes was realized from a wide range of terminal and internal allenes.
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