Journal
CHEMISTRY OF HETEROCYCLIC COMPOUNDS
Volume 48, Issue 12, Pages 1793-1800Publisher
SPRINGER
DOI: 10.1007/s10593-013-1210-8
Keywords
1-arylimidazoles; boron trifluoride; imidazole N-oxides; heterocyclization; N-oxide reduction
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A method has been developed for the synthesis of 1-arylimidazoles lacking a substituent at position 2, featuring the preparation of 1-arylimidazole N-oxides stabilized as boron trifluoride derivatives, with subsequent reduction to the desired imidazoles. This method permits broad variation of the substituents in the aryl part of these molecules.
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