Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 25, Pages 7418-7421Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201502584
Keywords
asymmetric synthesis; C-C activation; homogeneous catalysis; nitrogen heterocycles; rhodium
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Funding
- MEXT
- JST
- Grants-in-Aid for Scientific Research [24655077, 14J03286] Funding Source: KAKEN
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3-Hydroxypiperidine scaffolds were enantioselectively constructed in an atom-economical way by sequential action of light and rhodium upon N-allylglyoxylamides. In a formal sense, the allylic C-H bond was selectively cleaved and enantioselectively added across the ketonic carbonyl group with migration of the double bond (carbonyl-ene-type reaction).
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