Journal
CHEMISTRY LETTERS
Volume 43, Issue 2, Pages 204-206Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.130929
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Funding
- MEXT of Japan [452/17013009, B/20350104, A/23245046]
- Japan Society for the Promotion of Science for Young Scientists [11J07791, 25.192]
- National Science Foundation [DMR-1206459]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1206459] Funding Source: National Science Foundation
- Grants-in-Aid for Scientific Research [13J00192, 20350104, 23245046] Funding Source: KAKEN
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Thermoreversible gelation of ionic liquids (lLs) was demonstrated using a well-defined ABA triblock copolymer. The ABA triblock copolymer consisted of poly(phenylethyl methacrylate) terminal A blocks and a poly(methyl methacrylate) middle B block. Temperature-tunable thermosensitive sol-gel transition, i.e., low-temperature-sol high-temperature-gel, can be realized because of the lower critical solution temperature aggregation behavior of the A blocks. The sol gel transition behavior of polymer-IL composites can be precisely controlled not only by changing the chemical structure of the A blocks but also by changing that of the ILs.
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