Journal
CHEMISTRY LETTERS
Volume 43, Issue 7, Pages 1029-1030Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.140248
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [21108006]
- Japan Society for the Promotion of Science (JSPS) [25248014]
- JSPS
- Grants-in-Aid for Scientific Research [25248014, 26288021, 21108006] Funding Source: KAKEN
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A cyanide-bridged tetranuclear complex, [Co2Fe2(CM6-(tP*)(2)(dmbPY)(4)](PF6)(2)center dot 4CH(3)CN (1 center dot 4CH(3)CN) (tp*: hydrotris-(3,5-dimethylpyrazol-1-yl)borate and dmbpy: 5,5'-dimethyl-2,2'-bipyridine), was synthesized and its magnetic properties were investigated. Magnetic susceptibility measurements revealed that 1 exhibited an abrupt one-step thermal phase transition based on electron-transfer-coupled spin transition (ETCST) and light-induced ETCST at low temperature.
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