4.3 Article

Porphyrin-based Coordination Polymer Composed of Layered Pillarless Two-dimensional Networks

Journal

CHEMISTRY LETTERS
Volume 43, Issue 7, Pages 1161-1163

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.140275

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Funding

  1. MEXT, Japan [22108524, 24108735]
  2. Royal Society
  3. Grants-in-Aid for Scientific Research [24108735, 22108524] Funding Source: KAKEN

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Single crystals of a layer-structured coordination polymer, BNAS-11 [ZnTCPP(H2O)Zn-2(H2O)(2)] (ZnTCPP: 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinatozinc(II)), were obtained. Tetratopic ZnTCPP molecules are connected through dimer zinc paddle-wheel secondary building units and form a two-dimensional (2D) network with square grids. The layers are stacked electrostatically without the need of binding pillar ligands.

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