4.3 Article

Synthesis of Highly Conjugated Dinuclear Ru Complexes Bridged by a Novel N2-N3 Ligand and Their Application in Photocatalytic Oxygenation of Sulfides

Journal

CHEMISTRY LETTERS
Volume 43, Issue 3, Pages 290-292

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.130966

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Funding

  1. Japan Science and Technology Agency, PRESTO (Precursory Research for Embryonic Science and Technology)
  2. Naito Foundation
  3. JSPS KAKENHI [24550071]
  4. Grants-in-Aid for Scientific Research [24550071] Funding Source: KAKEN

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Highly conjugated dinuclear Ru complexes bridged by a novel N2-N3 ligand were synthesized. The dinuclear Ru complexes were active toward photoredox-mediated catalytic sulfide oxygenation via proton-coupled oxidation in neutral conditions. Various control experiments have shown that both dinuclear motif and light are essential for the reaction.

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