Journal
CHEMISTRY LETTERS
Volume 42, Issue 10, Pages 1308-1310Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.130521
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Funding
- MEXT [22105005, 24106718, 23685019, 23350041]
- Takeda Science Foundation
- Asahi Glass Foundation
- Grants-in-Aid for Scientific Research [23685019, 24106718, 22105005, 23350041] Funding Source: KAKEN
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1-Sulfonyl-1,2,3-triazoles undergo a Doyle-Kirmse reaction upon treatment with allylic sulfides in the presence of a rhodium(II) catalyst to afford alpha-allyl-alpha-sulfanylimines. Terminal alkynes are regioselectively multifunctionalized by the introduction of C-N, C-S, and C-C bonds through a one-pot sequence consisting of a [3 + 2] dipolar cycloaddition reaction with azide and subsequent Doyle-Kirmse reaction.
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