Journal
CHEMISTRY LETTERS
Volume 42, Issue 4, Pages 328-334Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.130189
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Funding
- KAKENHI from the Japan Society for the Promotion of Science (JSPS)
- MEXT, Japan
- JSPS
- Grants-in-Aid for Scientific Research [10J07500, 21225003] Funding Source: KAKEN
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Desymmetrization self-assembly of symmetric building blocks is a powerful method to construct elaborate metallosupramolecular architectures. Herein several examples are given to discuss how to build up self-assembled complexes with low symmetry, focusing on 1) stabilization of local structural motifs by template molecules and/or interligand interactions, 2) rigidity regulation of ligand scaffolds, and 3) control of intermediate complexation conditions. Unsymmetrically assembled supramolecular host complexes exhibit unique functions reflecting their structural frameworks.
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