4.3 Article

Synthesis of Cu2(OH)PO4 Crystals with Various Morphologies and Their Catalytic Activity in Hydroxylation of Phenol

Journal

CHEMISTRY LETTERS
Volume 42, Issue 7, Pages 772-774

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.130135

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Funding

  1. National Natural Science Foundation of China [20841003, 20741001]
  2. New Century Outstanding Scholar Supporting Program

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Copper hydroxyphosphate (Cu-2(OH)PO4) crystals with various morphologies have been successfully synthesized by a simple hydrothermal method, using different organic amines as the morphology-controlling agents. These Cu-2(OH)PO4 crystals were used as catalysts for phenol hydroxylation by H2O2, and they showed distinct activities. The sheet morphology of Cu-2(OH)PO4 crystals with a large percentage of reactive facets ({011} facets) exhibited enhanced catalytic activity in hydroxylation of phenol.

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