4.3 Article

Application of a Bis(silylene) Nickel Complex as Precatalyst in C-C Bond Formation Reactions

Journal

CHEMISTRY LETTERS
Volume 42, Issue 3, Pages 286-288

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2013.286

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Funding

  1. Cluster of Excellence Unifying Concepts in Catalysis [EXC 314/1]
  2. Deutsche Forschungsgemeinschaft
  3. Alexander Humboldt Foundation

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In the present study the catalytic performance of a nickel complex stabilized by an oxygen-bridged bis(silylene) ligand was examined in cross-coupling reactions of aryl halides with organometallic zinc and Grignard reagents. Good to excellent catalytic activity was observed for a variety of substrates with this system.

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