4.3 Article

Palladium-catalyzed Carboboration: Borylative Coupling of Alkynes with Alkenes through Activation of Boron-Chlorine Bonds

Journal

CHEMISTRY LETTERS
Volume 42, Issue 5, Pages 538-540

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.130131

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Funding

  1. MEXT

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Alkynes tethered to a chloro(diisopropylamino)boryl group undergo palladium-catalyzed borylative coupling with styrenes and acrylates, giving substituted cyclic 1,3-dienylboronic acid derivatives in a stereoselective fashion.

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