4.3 Article

Electrogenerated Acid (EGA)-catalyzed Addition of Diaryl Disulfides to Carbon-Carbon Multiple Bonds

Journal

CHEMISTRY LETTERS
Volume 42, Issue 8, Pages 843-845

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.130255

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Funding

  1. Japan Society for the Promotion of Science
  2. Grants-in-Aid for Scientific Research [25410117, 24105522] Funding Source: KAKEN

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Addition of diaryl disulfides to carbon-carbon multiple bonds was achieved with a catalytic amount of an electrogenerated acid (EGA), which was produced by the electrolysis of Bu4N+B(C6F5)(4)(-)/CH2Cl2. The anti-addition products of two ArS groups across the carbon-carbon multiple bond were obtained in good yields.

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