Journal
CHEMISTRY LETTERS
Volume 42, Issue 10, Pages 1128-1130Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.130485
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Uehara Memorial Foundation
- Grants-in-Aid for Scientific Research [25620084] Funding Source: KAKEN
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We have developed sequential Zr/Cu catalysis involving regioselective hydroboration and electrophilic amination for the formal anti-Markovnikov hydroamination of terminal aryl alkynes. The reaction system can provide a facile access to enamines from terminal acetylenes with high regioselectivity under mild conditions.
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