4.3 Article

Exfoliation of Layered Octosilicate by Simple Cation Exchange with Didecyldimethylammonium Ions

Journal

CHEMISTRY LETTERS
Volume 42, Issue 1, Pages 80-82

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2013.80

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Funding

  1. Elements Science and Technology Project Functional Designs of Silicon-Oxygen-Based Compounds by Precise Synthetic Strategies
  2. Global COE program Practical Chemical Wisdom from MEXT, Japan

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Layered octosilicate was exfoliated by stirring didecyldimethylammonium-exchanged silicate in pentane with ultrasonication. The silicate framework was retained at least partly even after the exfoliation. Loosely arranged decyl groups in the interlayers probably induce the exfoliation. This exfoliation method should be applicable to other layered alkali silicates.

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