Journal
CHEMISTRY LETTERS
Volume 41, Issue 9, Pages 990-992Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2012.990
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Funding
- Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japan [24685018]
- Kyoto Technoscience Center
- Grants-in-Aid for Scientific Research [24685018] Funding Source: KAKEN
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We describe the practical optical resolution of rac-pseudo-ortho-dibromo[2.2]paracyclophane to obtain the parent compound for a variety of cyclophane-based planar chiral compounds such as enantiopure chiral ligand [2.2]PHANEPHOS. In addition, the obtained enantiopure planar chiral (R)- and (5)-pseudo-ortho-disubstituted [2.2]paracyclophanes can be used as the building blocks for optically active carbon-rich compounds.
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