Journal
CHEMISTRY LETTERS
Volume 41, Issue 6, Pages 622-624Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2012.622
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Funding
- Grants-in-Aid for Scientific Research [24102006] Funding Source: KAKEN
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A series of necklace-shaped dimethylsiloxane (DMS) polymers bearing a polyhedral oligomeric silsesquioxane (POSS) cage were synthesized from bifunctional POSS by two different synthetic routes. One-step or two-step polycondensation between POSS and dimethyloligosiloxane dichloride led to necklace polymers with constant chain lengths (n = 2-8). The ring-opening polymerization of octamethylcyclotetrasiloxane (D4) with POSS was also found to provide similar necklace-shaped polymers with dispersed chain lengths of DMS. The thermal properties, decomposition temperature (T-d5%), and glass-transition temperatures (T-g) of the polymers were strongly dependent on DMS chain length. The polymers with dispersed chain lengths gave higher T-g's than the polymers with corresponding constant chain lengths. The highest T-d5% reached 478 degrees C.
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