4.3 Article

Synthesis and Supramolecular Association of NCN-Pincer Pd-Complex-bound Norvaline Derivatives toward Fabrication of Controlled Metal Array

Journal

CHEMISTRY LETTERS
Volume 41, Issue 2, Pages 194-196

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2012.194

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Funding

  1. MEXT, Japan
  2. JSPS
  3. International Center for Integrated Research and Advanced Education in Materials Science
  4. MEXT
  5. Grants-in-Aid for Scientific Research [22550099, 22750136] Funding Source: KAKEN

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Novel NCN-pincer Pd-complex-bound norvaline derivatives were synthesized. The N- and C-termini-alkylated Pd-norvalines spontaneously assemble into fibrous aggregates to form supramolecular gels, in which the NCN-pincer Pd complex moieties assemble in a highly oriented manner.

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