Journal
CHEMISTRY LETTERS
Volume 41, Issue 2, Pages 157-158Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2012.157
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Funding
- Asahi Glass Fundation
- Ministry of Education, Culture, Sports, Science and Technology, Japan
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Highly diastereoselective reductive coupling reaction was achieved between an aldehyde and a norbomene to afford an alcohol compound using a nickel/phosphine catalyst system in the presence of a reducing agent. The combination of a PCy3 ligand and triethylborane as the reducing agent proved effective for the reaction. A wide range of aldehydes were found to participate in the reaction with high diastereoselectivities.
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