4.3 Article

Electrophilic Aromatic Substitution of Arenes with CO2 Mediated by R3SiB(C6F5)4

Journal

CHEMISTRY LETTERS
Volume 41, Issue 9, Pages 913-914

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2012.913

Keywords

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology, Japan [23550115]
  2. Grants-in-Aid for Scientific Research [23550115] Funding Source: KAKEN

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The Friedel Crafts-type carboxylation of arenes has been achieved by activating CO2 with silylium borates. The reaction exhibits broader substrate applicability than does our previously reported AIX(3)/R3SiX-mediated carboxylation.

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