Journal
CHEMISTRY LETTERS
Volume 41, Issue 11, Pages 1475-1477Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2012.1475
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Funding
- Tsukuba Corporation Research Laboratory, NOF Corporation
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Thiocarbohydrazides and oxalyl dihydrazides are used as positive electrode active materials for rechargeable lithium batteries with a lithium metal negative electrode. These compounds exhibit a two-electron migration in the positive electrode, yielding very large capacities of 482 and 450 mA h g(-1) respectively, by virtue of their small molecular weights (106 and 118, respectively). Additionally, tetramethyl- and diphenyl-substituted derivatives are used; the former compounds exhibit two-electron migrations with capacities of 310 and 300 mA h g(-1) while the latter compounds exhibit three- to four-electron migrations with large capacities of both 359 mA h g(-1).
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