Journal
CHEMISTRY LETTERS
Volume 41, Issue 9, Pages 866-867Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2012.866
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Funding
- Japan Chemical Innovation Institute (JCII)
- Ministry of Education, Culture, Sports, Science and Technology
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An atom-efficient and green synthetic route to highly valuable imides (54-92% yields) from terminal alkynes and amides has been developed. This new route is composed of two consecutive reactions, that is, (i) the reported Cu(OH)(2)-catalyzed cross-coupling of terminal alkynes and amides to ynamides and (ii) the Sn-W mixed oxide-catalyzed regioselective hydration of ynamides.
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