Journal
CHEMISTRY LETTERS
Volume 41, Issue 5, Pages 541-543Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2012.541
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Funding
- MEXT, Japan
- Grants-in-Aid for Scientific Research [21106012, 21106001, 21106002, 10J00648] Funding Source: KAKEN
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Based on space integration using a flow microreactor system, the title unsymmetrically substituted pyracenes with an extremely long C C bond [1.714(2)-1.739(4)angstrom] are readily accessible, whose structures demonstrate nonadditive substituent effects on expanding the polyarylated C-1-C-2 bond in crystal. The bond lengths rather exhibit correlation with the eclipsing degree of the C-sp3-C-sp3 bond, which is more affected by the intermolecular factors such as crystal packing.
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