Journal
CHEMISTRY LETTERS
Volume 41, Issue 2, Pages 130-134Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2012.130
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Transition metal catalysis plays a leading role in C(sp(2))-C(sp(2)) bond formation through substitution reactions. On the other hand, a similar type of substitution reaction has recently been achieved without the aid of transition-metal catalysts. In this review, recent transition-metal-free coupling reactions of aryl halides with arenes, alkenes, or aryl Grignard reagents are summarized in view of S(RN)1 reaction.
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