Journal
CHEMISTRY LETTERS
Volume 40, Issue 12, Pages 1440-1442Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2011.1440
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Funding
- JST PRESTO
- Japan Society for the Promotion of Science
- Grants-in-Aid for Scientific Research [23750049] Funding Source: KAKEN
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The regio- and stereoselective synthesis of allylsilane derivatives bearing a tetrasubstituted olefin was achieved using 2,2-diborylethylsilane as a key intermediate. The regioselective deprotonation of a 2,2-diborylethylsilane with LTMP and the subsequent nucleophilic addition to ketones gave corresponding allylsilanes in good to excellent yield with excellent stereoselectivity.
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