Journal
CHEMISTRY LETTERS
Volume 40, Issue 9, Pages 916-918Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2011.916
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- MEXT
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Ruthenium-catalyzed C-H silylation of methylboronic acid was achieved by use of 2-(1H-pyrazol-3-yl)aniline as a removable alpha-directing modifier on the boron atom. Cross-coupling of the product, i.e., (phenyldimethylsilyl)methylpinacolborane, with aryl halides proceeded in the presence of a [PdCl2(dppf)] catalyst and CsOH as a base.
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