Journal
CHEMISTRY LETTERS
Volume 40, Issue 9, Pages 975-977Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2011.975
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Funding
- Global COE Program [B01]
- MEXT, Japan
- Grants-in-Aid for Scientific Research [22350016, 11J00469] Funding Source: KAKEN
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Due to the high-lying HOMO of the substituents and the low-lying LUMO inherited by the heterocyclic skeleton, the title quinoxalinoquinoxalines 1 exhibit absorption bands which extend to the NIR region, whereas the dihydro derivatives 2 are less colored but emit strong green fluorescence. Thus, the present pairs can serve as novel redox dyes for drastic spectral changes.
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