Journal
CHEMISTRY LETTERS
Volume 40, Issue 6, Pages 600-602Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2011.600
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- MEXT
- JSPS, Japan
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Oxidative coupling of benzylamines with internal alkynes accompanied by dehydrogenation and dehydrogenative cyclization proceeds efficiently under rhodium catalysis to selectively give the corresponding 3,4-substituted isoquinoline derivatives. The procedure is also applicable to the reactions of (1-naphthylmethyl)amine with diaryl- and dialkylacetylenes to construct benzo[h]isoquinoline and benzo[e]isoindole frameworks, respectively.
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