Journal
CHEMISTRY LETTERS
Volume 40, Issue 9, Pages 1018-1020Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2011.1018
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Science Research Promotion Fund
- Network Joint Research Center for Materials and Devices
- Grants-in-Aid for Scientific Research [21350056, 23655090, 22106540, 22750096] Funding Source: KAKEN
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Ruthenium-catalyzed ortho-selective acylation of arylpyridines with acyl chlorides via C-H bond cleavage is described. Aromatic acyl chlorides as well as alpha,beta-unsaturated acyl chlorides were coupled with arylpyridines to give aromatic ketones in the presence of [RuCl2(PPh3)(3)] as a catalyst and potassium carbonate as a base.
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