4.3 Article

Development of pH-Sensitive Spin-crossover Iron(II) Complex Films, [FeII(diAMsar)]-Nafion: Manipulation of the Spin State by Proton Concentration

Journal

CHEMISTRY LETTERS
Volume 40, Issue 8, Pages 888-889

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2011.888

Keywords

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology, Japan [22350057]
  2. Grants-in-Aid for Scientific Research [23750056, 22350057] Funding Source: KAKEN

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We newly synthesized transparent films composed of pH-sensitive spin-crossover complex [Fe-II(diAMsar)] (diAMsar: 1,8-diaminosarcophagine) and an ion-exchange polymer, Nafion, having different colors corresponding to proton concentration. The UV-vis spectroscopic measurements revealed that the films, which were provided under pH 4, 7, and 10 conditions, showed the spin state depending on pH.

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