4.3 Article

Electron Mobility in a Mercury-mediated Duplex of Triazole-linked DNA (TLDNA)

Journal

CHEMISTRY LETTERS
Volume 40, Issue 3, Pages 318-319

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2011.318

Keywords

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Funding

  1. KAKENHI [21685005, 20108015, 22550094, 21108513]
  2. Global CUE Program (Molecular Complex Chemistry)
  3. JSPS
  4. Grants-in-Aid for Scientific Research [23550041, 20108015, 21108513, 21685005] Funding Source: KAKEN

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A metal-ion-mediated duplex of triazole-linked DNA ((TL)DNA) was synthesized via thymine-mercury(II)-thymine (T-Hg-T) base pairing. The electron-transport properties of the mercury-mediated duplex deposited on a solid substrate were determined by time-resolved microwave conductivity (TRMC) measurements.

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