Journal
CHEMISTRY LETTERS
Volume 40, Issue 5, Pages 489-491Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2011.489
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Funding
- National Natural Science Foundation of China [20902076]
- One Hundred Talent Project of Hunan Province
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A ruthenium-catalyzed tertiary-amine formation was developed using the borrowing hydrogen strategy. Various tertiary amines were obtained efficiently from nitrites and primary alcohols. Two possible pathways were found for the tertiary-amine formation under RuCl3/dppf catalytic conditions. The nitrites mainly act as a nitrogen source in this kind of transformation.
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