Journal
CHEMISTRY LETTERS
Volume 40, Issue 3, Pages 279-281Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2011.279
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- DST, India [SR/S1/PC/26/2008]
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The selectivity and sensitivity of N,N'-bis(4-diethylaminosalicylidene)hydrazine (sensor 1) toward Cu2+ ion have been established both by distinct naked-eye color change as well as UV-vis spectrophotometry. Sensor 1 formed 1:1 complex with Cu2+ ion where the most stable s-trans form of the sensor is trapped in the high energy conformer. Single-crystal X-ray structure of sensor 1 supports its s-trans conformation. Theoretical calculations support well the experimental result.
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