4.3 Article

Monovalent Nickel Complex Bearing a Bulky N-Heterocyclic Carbene Catalyzes Buchwald-Hartwig Amination of Aryl Halides under Mild Conditions

Journal

CHEMISTRY LETTERS
Volume 40, Issue 9, Pages 1036-1038

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2011.1036

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Funding

  1. Japan Society for the Promotion of Science [22550104]
  2. Grants-in-Aid for Scientific Research [22550104] Funding Source: KAKEN

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Monovalent nickel complex bearing a bulky N-heterocyclic carbene (NHC) and triphenylphosphine was synthesized and demonstrated to catalyze the Buchwald-Hartwig amination of aryl halides with diarylamines to form triarylamines under mild conditions.

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