4.3 Article

CAN/I2-catalyzed Chemoselective Synthesis of Thiosulfonates by Oxidation of Disulfides or Thiols

Journal

CHEMISTRY LETTERS
Volume 39, Issue 4, Pages 368-369

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2010.368

Keywords

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Funding

  1. National Key Technology RD Program [2007BAI34B00]
  2. Natural Science Foundation of Zhejiang Province [Y4080107]

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CAN/I-2 promoted synthesis of thiosulfonates by oxidation of disulfides and thiols with high chemoselectivity and excellent yields in wet poly(ethylene glycol) (PEG-400). The overall process is simple, practical, and it provides convenient access to thiosulfonates.

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