Journal
CHEMISTRY LETTERS
Volume 39, Issue 6, Pages 558-560Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2010.558
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Styrene derivatives underwent dehydroborylation with naphthalene-1,8-diaminatoborane [(dan)BH] in the presence of a cationic rhodium complex, giving beta-borylstyrene derivatives in good yields. Thus prepared beta-borylstyrenes bearing a chlorine or B(pin) group on their aromatic rings were utilized for the synthesis of highly conjugated molecules through stepwise cross-coupling, taking advantage of the dan group as an effective protective group for a boronyl group.
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