Journal
CHEMISTRY LETTERS
Volume 39, Issue 8, Pages 867-869Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2010.867
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- Asahi Glass Foundation
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A CF3 group attached to an alkene functionality was activated by a zero-valent niobium catalyst to generate niobium alkenylcarbenoid species. The niobium carbenoid species then underwent insertion to an internal aromatic C-H sigma bond to give indene derivatives in good yields. Isomerization in terms of the alkene geometry was also observed.
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