4.3 Article

Redox Behavior of Ruthenium(Bipyridine)(Terpyridine)(Carbonyl) Complex-modified Carbon Electrode and Reactivity toward Electrochemical Reduction of CO2

Journal

CHEMISTRY LETTERS
Volume 39, Issue 11, Pages 1134-1135

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2010.1134

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology, Japan [20002005]

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Electrochemical reduction of a diazonium complex [Ru-(bpy)(trpy-ph-N-2(+))(CO)](PF6)(3) ([1](PF6)(3)) (bPY = dine, trpy-ph-N-2(+) = 4-(2,2' 6',2-terpyncline-4'-yl)benzenedi-azonium) using a GC electrode forms multdayer films of the complexes on the electrode surface, on which the reduced form of the complex showed strong affinity toward CO2

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