Journal
CHEMISTRY LETTERS
Volume 39, Issue 5, Pages 527-529Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2010.527
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Funding
- Zhejiang University of Technology Younger Scholars Program
- Zhejiang Provincial Undergraduate Innovative Experimental Program
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Cycloaddition of various aryl isocyanates with oxiranes was realized in the presence of 50 mol % MgI2 etherate in a mild, efficient, and highly regioselective manner, which afforded 3-aryloxazolidin-2-one. Solvents (i.e., THF) and amounts of MgI2 etherate catalyst played the critical roles for the unique reactivity of this catalytic system.
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