4.3 Article

Covalent Attachment of Organic Groups onto Single-walled Carbon Nanotubes via Copper(I)-promoted Radical Addition

Journal

CHEMISTRY LETTERS
Volume 39, Issue 9, Pages 1000-1001

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2010.1000

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Funding

  1. Shanghai Leading Academic Discipline Project [J51504]
  2. Shanghai Education Commission [06OZ025]
  3. Shanghai Institute of Technology [Yj-2006-19]

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Functionalization of single-walled carbon nanotubes (SWNTs) via atom-transfer radical addition in the presence of copper(I/II) redox systems allows for covalent attachment of a variety of different groups such as carboxylate and aryl. Modified SWNTs were characterized by ATR-IR, TG-MS, as well as Raman spectra, clearly indicating the formation of covalent bonding between organic groups and nanotubes.

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