4.3 Article

One-step Conversion of CO32-LDH (Layered Double Hydroxide) into Anion-exchangeable LDHs Using an Acetate-buffer/Salt Method

Journal

CHEMISTRY LETTERS
Volume 39, Issue 6, Pages 591-593

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2010.591

Keywords

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Funding

  1. JSPS (Japan Society for the Promotion of Science) [20550142]
  2. Grants-in-Aid for Scientific Research [20550142] Funding Source: KAKEN

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By carrying out decarbonation of CO32--type MgAl-LDH (layered double hydroxide) using an acetate-buffer/salt solution under N-2 flow, CO32- LDH was successfully converted into ClO4- and NO(3)(-)LDHs, which contain only a little residual CO32-, in one step under mild conditions. Due to the superior anion-exchangeability, they serve as suitable intermediates for the preparation of LDH hybrids.

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