4.3 Article

Thiofluorination of Carbon-Carbon Multiple Bonds Using Electrochemically Generated ArS(ArSSAr)+BF4-

Journal

CHEMISTRY LETTERS
Volume 38, Issue 12, Pages 1186-1187

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2009.1186

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Funding

  1. Japan Society for the Promotion of Science

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The reaction of alkenes and alkynes with ArS(ArSSAr)(+)BF4-, which was generated and accumulated by the low-temperature anodic oxidation of ArSSAr in Bu4NBF4/CH2Cl2, led to the addition of an ArS group and fluoride across the carbon-carbon multiple bond to give thio-fluorinated compounds in good yields.

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