Journal
CHEMISTRY LETTERS
Volume 38, Issue 11, Pages 1052-1053Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2009.1052
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Funding
- MEXT
- JSPS
- Nagoya University
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The stereoselective direct Henry reaction of pyruvates mediated by chiral P-spiro tetraaminophosphonium salts is described. High levels of diastereo- and enantioselectivities have been achieved by the use Of L.-valine-derived (P,S)-2e bearing para-chlorophenyl groups as a precatalyst.
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