4.3 Article

B12-TiO2 Hybrid Catalyst for Dehalogenation of Organic Halides

Journal

CHEMISTRY LETTERS
Volume 38, Issue 5, Pages 468-469

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2009.468

Keywords

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japan
  2. New Energy and Industrial Technology Development Organization (NEDO) of Japan

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A cobalamin derivative, cobyrinic acid, was effectively immobilized on TiO2, and the hybrid TiO2 was characterized by UV-vis, XPS, MALDI-TOFMS as well as TEM analysis. The hybrid TiO2 exhibits high reactivity for dehalogenation of various organic halides such as phenethyl bromide, benzyl bromide, and 1,1-bis(4-chlorophenyl)-2,2,2-trichloroethane (DDT) under irradiation with UV light at room temperature.

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