4.3 Article

Formation and Structure of Perfluorosulfonated Ionomer Thin Film on a Graphite Surface

Journal

CHEMISTRY LETTERS
Volume 38, Issue 9, Pages 884-885

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2009.884

Keywords

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Funding

  1. JSPS [18205016]
  2. Global COE Program
  3. Promotion of Novel Interdisciplinary Fields Based on Nanotechnology and Materials
  4. Ministry of Education. Culture. Sports, Science and Technology, Japan
  5. Grants-in-Aid for Scientific Research [18205016] Funding Source: KAKEN

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Adsorption process and structure of perfluorosulfonated acid (PFSA) polymer on a highly oriented pyrolytic graphite (HOPG) surface were elucidated by an in situ tapping mode atomic force microscope (AFM). Micellar aggregates of PFSA polymers first randomly adsorbed on a bare HOPG surface, and then the adsorbed aggregates extended under the influence of atomic arrangement of HOPG Surface, to form two-dimensionally ordered domains.

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