Journal
CHEMISTRY LETTERS
Volume 38, Issue 11, Pages 1054-1055Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2009.1054
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Funding
- Mukai Science and Technology Foundation
- Japan Society for the Promotion of Science [21680043]
- Grants-in-Aid for Scientific Research [21680043] Funding Source: KAKEN
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Thermoresponsive polyphosphoesters bearing acetoxymethyl (AM) groups were newly synthesized. The polymers had the LCST-type cloud point in aqueous media, and the thermoresponsive phenomena was influenced by the condition of the medium. About 40% of the AM groups in the polymers were cleaved in contact with esterase for 24 h in phosphate buffer solution. This was significant compared with the spontaneous cleavage in the buffer solution. After the cleavage of the AM groups, the thermoresponsivity of the polyphosphoesters was diminished.
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