Journal
CHEMISTRY LETTERS
Volume 38, Issue 12, Pages 1160-1161Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2009.1160
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Funding
- MEXT, Japan [19105003, 21655043]
- Grants-in-Aid for Young Scientists [A09324100]
- Grants-in-Aid for Scientific Research [21655043] Funding Source: KAKEN
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Two redox-active poly(oxoammonium salt)s were synthesized via chemical oxidation of a TEMPO-substituted polymer, or conventional radical polymerization of the oxoammonium monomer, respectively. The diode-structured thin film device composed of poly(oxoammonium salt) with radical conc. of 6-43% exhibited a resistive switching behavior (ON-OFF ratio > 10(3)), in contrast to the radical-free poly(oxoammonium salt), which revealed that the coexistence of radical/oxoammonium salts contributed to a significant change in I-V characteristics.
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