4.3 Article

Multiphase Photocatalytic Oxidation in a Microreactor

Journal

CHEMISTRY LETTERS
Volume 38, Issue 8, Pages 846-847

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2009.846

Keywords

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology of Japan [20510115]
  2. New Energy and Industrial Technology Development Organization (NEDO)
  3. Grants-in-Aid for Scientific Research [20510115] Funding Source: KAKEN

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Photocatalytic oxidation of p-chlorophenol and toluene under gas-liquid-solid multiphase flow conditions was investigated by using a photocatalytic microreaction system. By loading both gaseous and liquid samples simultaneously into a microchannel with a photocatalytic titanium dioxide thin layer therein, a gas-liquid-solid multiphase annular flow was generated. The reaction yield was greatly enhanced with decreasing thickness of liquid layer because of improved efficiency of interaction and mass transfer between different phases.

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